Lignin Collaborative study with the IBioIC and the University of Glasgow

Lignin Samples Sonichem

Lignin, ‘Nature’s Glue’ from Sawdust targets the Sustainable Chemicals Challenge

A team of researchers in Scotland is supporting a clean tech startup to transform co-products from the forestry sector into high-value, eco-friendly alternatives to chemicals used in everyday products.

Sonichem’s ambition is to reduce the reliance on petrochemical-derived ingredients in industries such as cosmetics, packaging and pharmaceuticals. Using its patented ultrasound technology to break down forestry co-products – including woodchips and sawdust – the company extracts natural compounds that can be transformed into green alternatives to essential chemicals.

A recent feasibility study funded by the Industrial Biotechnology Innovation Centre (IBioIC), with support from the University of Glasgow, has helped the business to take its technology to the next stage.

The UK generates approximately 4.5 million tonnes of wood co-products every year[1]. Only 55% of logs that enter a sawmill become usable construction timber, while the remainder ends up as low-value co-products such as woodchips and sawdust.

The premium target organic chemical being collected through Sonichem’s process is lignin – a polymer that acts like a natural glue, binding the cells and fibres in trees and other types of plants together. This property makes it well-suited for use in products such as resins, films, coatings and foams.

While naturally occurring lignin from sawdust is not immediately transferrable to these types of products, the researchers used a series of chemical reactions to create compounds that better matched the synthetic counterparts and could be used in manufacturing.

Andy West, chief chemist at Sonichem, said: “Compounds derived from petrochemicals are the building blocks for so many of the products we use every day, but to achieve net zero that needs to change. Trees are a great natural resource that could become part of the supply chain and lignin, in particular, is highly versatile and can be used in almost any setting. But, it is the natural glue that holds a tree together, which makes it difficult to extract. In the past, we explored various methods before developing the ultrasound technology to do so effectively.

“The next step in the process is about engaging with both the chemical manufacturers, as well as the forestry sector, to ensure that the right number and type of trees are planted now to secure the availability of the product for years to come. This project has been an important stage in the commercial development of our offering and the creation of our first biorefinery plant.”

Professor Dave Adams from the school of chemistry at the University of Glasgow, said: “Working with Sonichem, we have been able to modify the base lignin extracted from sawdust to turn it into a range of more useful chemicals. Of the five routes we tried, all five worked well, which is highly promising and gives the business the information needed to scale up this initial work to a commercial level.”

Dr Liz Fletcher, director of business engagement at IBioIC, added: “Scotland’s forestry sector is worth over £1 billion to the economy, but there is potential to see this grow by using the biomass that sawmills generate in manufacturing. Sonichem is a great example of a business looking at alternatives to petrochemicals from a feedstock otherwise used for low value applications. Up to 270 million tonnes of synthetic resin were used globally last year, highlighting the sheer scale of the opportunity to improve the sustainability of the chemicals sector.”

[1] Source: Wood Recyclers’ Association

Creating Sustainable Composites From Sawdust

Foresty and Timber News October 2022
Sustainable composites from sawdust article

The Green Revolution, creating sustainable composites from sawdust

Forestry and Timber News, October 2022 – Wood in the Circular Economy Edition

The Green Revolution

Carbon is the backbone of so many everyday materials and products that the chemical industry producing these products accounts for around 6% of global petroleum use. Societal concerns around climate change and decarbonization are driving what industry and policy makers are calling the Green Revolution, a movement in manufacturing from black petro-sourced carbon to green bio-sourced carbon.

Global brands including Unilever, PepsiCo and L’Oreal are investing billions of pounds to remove fossil-derived ingredients from their products and packaging over the next 5-10 years, significantly increasing demand for bio-derived alternatives. However, with natural resource depletion, increasing strain on global supply chains and an ever-growing global population, there are significant sustainability concerns regarding the use of food crops in chemical production. Focus instead is shifting towards the use of low value co-products from agricultural and forestry operations as a more suitable source of biochemicals.

Against this backdrop, Sonichem’s mission is to maximise the value of underutilised resources. To achieve this, Sonichem have developed Sonichem an award-winning low-energy ultrasonic process to convert woody biomass into chemicals. The Sonichem process generates almost zero waste, is water-use neutral, and produces three high-value products (cellulose, sugar syrup and lignin).

Wood: Nature’s Composite

The fibrous or woody component of plants and trees is called lignocellulose. The word derives from ‘Lignum’, the Latin name for wood, and is essentially nature’s composite. Wood consists of three components: cellulose fibres together with hemicellulose form a matrix which in turn is bound together by an aromatic biochemical called lignin. In nature this complex chemical structure of three biochemicals results in a solid cell wall that is resistant to wind, water, pests, and sunlight. When separated from each other these biochemicals are known as bio-based platform biochemicals and have wide market potential.

For many years, cellulose has been extracted from wood for the pulp and paper industry. Bio-Sep’s ultrasonic process produces a crystalline cellulose which is a high value speciality chemical with applications in food and beverages, cosmetics, and performance composites. 

Lignin is the world’s second most abundant biopolymer after cellulose. It is nature’s binding material, the substance that gives plants and trees their structural integrity and strength. Its aromatic structure makes it the most suitable biochemical to replace a toxic petrochemical called phenol, which is commonly used in resins, composites, coatings, and adhesives. Fluctuations in the price of phenol due to changes in oil price, and concerns about the toxic exposure of workers to phenol during the manufacturing process, make lignin an attractive bio-derived alternative. Natural lignin could be used for a phenolic replacement to make sustainable resins for use in, for example, the chipboard industry; the chips of wood could be held together with a resin made from lignin. Lignin as an eco-substitute not only reduces the carbon footprint and toxicity for manufacturers but also provides additional performance benefits such as fire resistance and UV protection.

The UK’s composite challenge is an opportunity

Humans have been making composite materials for years, starting thousands of years ago with a mud brick made from mud and straw, evolving to today’s materials such as concrete –a matrix of small stones bound by cement and lightweight materials such as carbon fibre.   

Composites are a high growth industry in the UK across sectors such as construction, aeronautics, and now renewable energy with wind turbines being made in the UK.  Composites UK estimates the UK composites industry was valued at £16.64bn in 2020. Added to this, UK composites companies are increasingly focused on biomaterial use for their sustainability strategy. According to Innovate UK, a lack of local supply of these biomaterials is one of their biggest challenges.

Supply chain issues over the last few years combined with the environmental footprint of shipping means that the industry is clamouring for a ‘reshoring’ of their input materials. This challenge to the composite industry presents a huge market opportunity for suitable platform biochemicals. This includes lignin and cellulose produced in the UK from available biomass sources, the most abundant of which is sawdust from the forestry industry.

R&D for a new forestry based performance composite

Sonichem embarked on a Joint Industry Project together with iCAST (The innovation Centre of Applied Sustainable Technologies), the National Composite Centre (NCC), and the University of Bath for the production and testing of bio-based composites from cellulose and lignin. Market testing will be undertaken by Scott Bader, a global manufacturer of resins and composites.

The NCC are looking to enhance their experience and understanding of the properties and manufacture of novel, sustainable materials

For this project they will be testing the mechanical properties and performance of Sonichem produced lignin and cellulose blends as a composite binder/matrix material.

The University of Bath will be producing and testing concrete materials incorporating Sonichems products as admixtures. Early results from the project are looking promising with demonstrable performance benefits and carbon reduction potential.

This project will enable the identification of construction and composite applications for lignin and cellulose extracted from UK grown sawdust (generously supplied to Sonichem by James Jones & Sons). With tried and tested performance characteristics, the high growth UK composites industry could make use of these low carbon, renewable materials, to displace petrochemical materials, create a local biochemical supply chain, and enhance the sustainability of their products.

Q&A

 

How do you see biorefining contributing towards net zero in the next 10-30 years?

The world needs chemicals, plastics, composites, and household goods that are not derived from crude oil, with its unsustainable impact on the environment, or from food crops, but instead from sustainable sources such as forestry. Biorefining will enable a shift from fossil to renewable green carbon resources, helping decouple chemical production from fossil resources and reducing CO2 emissions.

Is there an appetite from manufacturers to shift processes to using natural biochemicals?

Absolutely. Manufacturers cannot see a future without sustainable chemicals. Consumer behavior and government regulations such as carbon taxes will drive the change. In the future it is unlikely that chemicals will be purchased without a life cycle analysis, carbon footprint analysis and traceable supply certificate.

What of Sonichem’s current work are you most excited to see the results from?

I am really looking forward to seeing the results from the aforementioned industry project where we will be producing and testing a composite product. We also have another project in the pipeline which will look deeper into lignin as a coating. I can see a future where we produce a waterproof, fire-resistant composite out of 100% forestry-produced biochemicals that can be recycled again by our process at end-of-life to create something new, resulting in truly circular green materials.

Business Insider’s most promising climate-tech startups 2022

Bio-Sep team

The 37 most promising climate-tech startups of 2022, from microplastics to toilets, according to top VCs

Bio-Sep was recommended as one of the 37 most promising climate tech start-ups, poised to take off by Tim Mills of ACF Investors when Business Insider asked investors which start-ups are doing well in 2022. 

Business Insider review article by Tasmin Lockwood and Julie Bort, Aug 30, 2022

Recommended by: Tim Mills, ACF Investors

Relationship to VCs: Portfolio

Founded: 2008

Headquarters: Leicestershire, UK

Total raised: £3.2 million, or around $3.7 million

What it does: Bio-Sep has created a way to break down biomass — namely sawdust — to extract renewable biochemicals. These biochemicals can replace the toxic petrochemicals present in cosmetics, pharmaceuticals, and personal-care products.

Why it’s poised to take off: “The products produced by chemical companies are essential to having a high quality of life — they are the foundation of everything from modern healthcare to technology. But it’s also an industry that has a lot of work to do when it comes to decarbonizing,” Mills said. “Bio-Sep’s technology could be key to that process, and the business model — turning £1 of sawdust into £6 worth of biochemicals — has the potential to be a highly profitable one.” 

Forestry and Timber News Article October 2021

Forestry and Timber News Article

A feature article on Bio-Sep’s technology in an environment and climate change special for Forestry and Timber News, the magazine for Confor members and the UK forest industries. Going green: unlocking valuable renewable chemicals from the by-products of forestry.

Forestry and Timber News Article Bio-Sep

Forestry and Timber News, October 2021. Bioeconomy focus piece for Confor

Forestry and Timber News Article Bio-Sep

Forestry and Timber News October 2021, Environment and Climate Change Special